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Towler, John. The Silver Sunbeam.
Joseph H. Ladd, New York: 1864. Electronic edition prepared from
facsimile edition of Morgan and Morgan, Inc., Hastings-on-Hudson,
New York. Second printing, Feb. 1974. ISBN 871000-005-9
Chapter I.
HISTORY OF PHOTOGRAPHY.
EVERY step, whether thoughtlessly or discreetly taken, is the
commencement of a new era in a man's life. As in a game of
chance-where either red or black must occur at the cessation of
motion in the finger of the dial-plate-the probability that red will
prevail over the black the next time, because black has occurred for
twenty times in succession, is not valid; it is equally probable
that black will be the successful color; so, in the game of life,
each successive move is a new beginning; and, as a single twirl of
the roulette may be the bane or the boon of the career of an
individual, so the slightest event, the most insignificant indeed,
may turn out to be the center of incalculable results. New
developments in the science of nature are not limited to their own
immediate sphere; they act and react upon the past and the future,
by illustrating phenomena that before were dark and not understood,
or by eliciting truths which hitherto were utterly unknown. Thus it
is that the invention of a machine, the improvement of a part of a
machine, or the discovery of some new chemical ingredient, may be
the date of the commencement of a new history. The verification of
this idea is pertinently made manifest in the change from the simple
double convex lens to the achromatic combination by Dolland;1 in the change from the signal telegraph
on the mountains to the electric telegraph in the closet; in the
improved application of steam by Watt; in the development of a
picture on the iodized plates of silver by the vapor of mercury; and
in the discovery of the hyposulphite of soda, cyanide of potassium,
pyrogallic acid, and the protosalts of iron. For from the moment
that chromatic and spherical aberration could be reduced, the
telescope and the microscope became altogether new instruments in
the hands of the natural philosopher, by which many crude notions
were quickly laid aside as false, and many new truths as quickly
denuded of their cloudy habiliments. Astronomy, one of the oldest of
sciences-one whose history can be traced back to the time of the
Chaldeans entered, at the time of the introduction of the achromatic
refracting telescope, upon an epoch as distinct in its history as
the transition from the system of Hipparchus to that of Copernicus.
At the same time, too, Physiology received a new impetus, by the
deductions drawn with the aid of the compound achromatic microscope,
so that Biology, since then, is gradually becoming more and more of
a science. By means of the former improved instrument, our eyes are
permitted to revel amid the enchanting scenes of the starry
firmament, by the latter to scrutinize the realms of minute
organisms of the earth, and by both to become acquainted with the
secrets of creation. For the investigator of nature in the great and
the minute, this is a new era in the history of the world as it
exists and acts. In like manner the age of steam and the telegraph
commenced a new history in the social existence and actions of men.
The mild tenets of the Gospel, which would seem to have no
connection whatever with the subject, have been more powerfully,
more efficaciously implanted in foreign soils, by the accessory
instrumentality of these agents, than by any preceding direct
operations of the missionary organization; the superiority of the
race of men that have invented and that ´yield such mighty
instruments for weal and for woe, is so distinctly marked, that
admiration and awe have engendered, in the minds of the ignorant and
less enlightened, respect for the creeds of religion and morality of
their superiors. Coexistent with the steam-engine and the electric
telegraph, and equally important as these in its influence on the
ways and means of life, is the art of sun-drawing. It is one of the
great wonders of the phenomena of created matter, so far eclipsing
the seven vaunted wonders of the world, that these recede into dark
nooks, like the wired dolls of an automata puppet-show. This art,
and the science that explains the different effects produced in its
manipulations, form the subject of the present volume. The art and
the science are of modern origin and of recent date.
Sun-drawing, Heliography, and Photography are synonymous
expressions for the same phenomenon, although etymologically the two
latter are somewhat different-heliography signifying
sun-writing, whilst the word photography signifies
light-writing. Not one of these expressions is strictly
correct, because actinic impressions can be obtained from rays
emanating from the moon, from artificial light, or the electric
spark. Actinic drawing would probably be the best name, although as
regards the representation of facts by words, it is immaterial for
the masses of mankind whether these words have an intrinsic or
root-meaning or not. The phenomena comprehended under any one of the
above synonymous expressions, depend immediately upon what is termed
light as the force or cause, and upon the property, which
only certain substances apparently possess, of being affected
according to the intensity of the light employed. The principal of
these substances are the salts of silver, the salts of
iron, bichromate of potassa, and certain resins, as the oil
of lavender and asphaltum. That light acts upon
organized substances is a phenomenon which must have been observed
by the first occupants of earth; they could not fail to remark the
brilliant hues on the side of an apple that received the direct rays
of the sun, and to contrast these resplendent mixtures of red,
crimson, green, purple, yellow, orange, and other colors, on the one
side, with the white, or greenish white, on the side exposed simply
to the diffused light of day. The variegated foliage of a tropical
clime, as contrasted with the continual merging into green,
according to the increase in latitude, gives evidence of the
influence of actinic action; and this change of green into white in
the leaves and stalks of similar plants, when supplied with heat and
air, and not with light, is a still stronger proof of heliographic
influence. But this species of influence is not limited to the
vegetable part of the earth; it is perceived, in all its beauties,
in the blooming cheeks of a maiden from Kaiserstuhl in the Black
Forest, or from the pasturing declivities of the Tyrolese Alps; and
its deficiency is quite as apparent in the pale, white, and lifeless
facial integuments of the unfortunate denizens of crowded cities, as
in the blanched stalks of celery in a dunghill, or the sickly white
filiform shoots of potatoes in a dark cellar. These phenomena are
full of wonder, no less so than any of the operations of sun-drawing
on paper or collodion, and quite as inexplicable; but they have long
failed to excite astonishment, from the frequency and commonness of
their occurrence.
The first remark in reference to the cause of the change of color
in silver salts is due to the distinguished Swedish chemist,
Scheele.2 He regarded the
blackening effect of chloride of silver, when exposed to the rays of
the sun, as caused by a species of reduction of the salt to the
metallic state and the accompanying formation of hydrochloric acid.
He undertook a course of experiments, to ascertain whether all the
colors of the spectrum had an equal influence in coloring or
blackening this salt, and arrived at the conclusion that the maximum
chemical or decomposing action of the spectrum was in the
neighborhood of the violet part, and that it gradually diminished
toward the red, where it was scarcely perceptible. The researches of
Scheele in this track terminated here; and no application of the
property of blackening of the chloride of silver to photogenic
purposes was made until after the lapse of several years.
In 1801 Rittert3 not only
corroborated the experiments of Scheele, but demonstrated that
chloride of silver was blackened to some distance external to the
spectrum, on the violet side. The scientific investigators of the
time repeated the experiments without any further developments.
Dr. Wollaston4 published a
report of experiments which he made with gum-guaicum, when acted
upon by the different colored rays of the spectrum. The violet rays
t[illegible]d I paper, stained yellow by a solution of this gum in
a[illegible]ol, to green, which was soon changed back to yellow by
the red rays; he discovered afterward, however, that the heat of the
red rays was sufficient of itself to reproduce the yellow color of
the tincture of the gum.
The same results were obtained by Bérard. He experimented
with half the spectrum at a time, which was condensed by a lens to a
focus, and made to impinge at this point upon chloride of silver.
The half next the violet, or more refrangible rays, were very
efficacious in discoloring this salt of silver; whilst the other
half, or red side, and least refrangible rays, although far more
luminous, produced no blackening effect. The experiments of Seebeck
seem to show that light transmitted through colored glass produced
the same general effect as the different colored rays of the
spectrum. He furthermore ascertained that a piece of paper dipped in
a rather concentrated and neutral solution of chloride of gold, in
the dark, was not reduced, as long as it was kept in the dark;
whereas if it had previously been exposed to the direct rays of the
sun, it gradually turned purple in the dark chamber. Sir Humphry
Davy observed that the oxide of lead, in a moist condition, is acted
upon very differently by the red and the violet rays of the
spectrum; by the latter, the puce-colored oxide is turned black-by
the former, red. He ascertained, too, that hydrogen and chlorine,
when exposed to the rays of the sun, frequently enter into
combination so vividly as to produce an explosion in the formation
of hydrochloric acid; but the two gases may be kept in contact, in
the dark, without undergoing much change. A solution of chlorine in
water remains unchanged, as long as it is kept out of the light; but
is soon converted into hydrochloric acid, by decomposing the water,
when exposed to the sun. A similar case of decomposition is effected
by light, when carbonic oxide and chlorine are exposed to light;
they then enter into combination chemically, condensing into a
substance denominated phosgene gas.
The preceding remarks comprehend the sum and substance of the
knowledge of the chemical effects of light previous to its
application to the taking of impressions of pictures by the salts of
silver or otherwise. It is true that a certain Hoffmeister published
some vague remarks about the sun being an engraver, several years
previous to Daguerre's publication; but they were the mere remarks
of one who probably thought the thing possible without possessing
the most distant idea of the mode of its effectuation. And in the
report which Arago made to the Chamber of Deputies in reference to
Daguerre's discovery, this distinguished philosopher mentions the
name of Charles as having been in possession of a process for
communicating pictures, by the aid of the sun, to prepared surfaces.
No publication has been discovered to corroborate this assertion,
and the details of the operation have never been disclosed.
The first recorded attempts by Wedgwood5 and Davy,6 to take pictures by the rays of the sun
on a prepared silver surface, were published in the year 1802. The
receptacle of the picture was either paper or leather, or some other
convenient material, stretched upon a frame, and sponged over with a
solution of nitrate of silver; over this prepared surface a painting
on glass was placed in direct contact and exposed to the rays of the
sun. It is evident that the picture thus obtained would be inverted
as to light and shade. The difficulty, which at this time could not
be overcome, was the fixing of the picture; and the process was
abandoned on this account. No chemical substance was known whose
peculiar properties were of such a nature as to dissolve the
unaltered salt of silver and leave the portions on which the image
was projected untouched or uninjured. These experiments of Wedgwood
were actually made several years previous to the publication in
1802; because at that date lie had been dead for seven years. The
surface prepared with nitrate of silver was not sensitive enough to
receive an impression in the camera obscura, although Sir Humphry
Davy succeeded in getting a very faint image in the solar
microscope, where the picture was very much condensed in size or
situated very near the focus of parallel rays. From that date to the
year 1814 not only no other publication appeared, but there are no
accounts of any one having prosecuted the study of sun-drawing. At
this time a new laborer entered the field of investigation and
directed all his mental energies to the discovery of means of making
sun-pictures. From the work of Daguerre, which was published several
years later, it appears that Niepce7 was the fast who obtained a permanent
sun-picture; to him we are indebted for the, first idea of a
fixing material; it was he who first employed silver and the
vapor of iodine. The process of Niepce had been so far perfected as
to admit the use of the camera, which, by reason of the want of
sensitiveness in the materials used; had remained a useless optical
arrangement. Niepce, in his experiments, discarded the use of the
silver salts, and substituted in their place a resinous substance
denominated the 11 Bitumen of Judea." He named his process
"Heliography," or " Sun-drawing." His pictures were produced by
coating a metal plate with the resinous substance above alluded to,
and then exposing this plate, under a picture on glass, or in the
camera, for several hours in front of the object to be copied. By
this exposure to light the parts of the bitumen which had been acted
upon by the rays underwent a change according to the actinic
intensity, whereby they became insoluble in certain essential
oils. By treatment afterward with these essences, as, for instance,
the oil of lavender, the picture was developed, the shadows
being formed by the brilliant surface of the metal exposed, by the
solvent action of the essential oil in those parts of the resin on
which the rays of light had not impinged; whilst the lights were
represented by the thin film of bitumen which had become altered and
insoluble in the oleaginous substance employed in fixing. Some of
the specimens produced by this method at this period exist still in
the British Museum; some of them are in the form of etchings, having
been acted upon probably by the galvanic current. It is evident that
Niepce was acquainted with a method of fixing his sun-drawings; but
his successes were limited to productions which now would be
regarded very trivial and unsatisfactory. After ten years' labor in
the prosecution of his favorite investigation, by some accidental
disclosure, Niepce became acquainted with Daguerre,8 who had been experimenting independently
in the same path. Daguerre's experiments with chemical processes and
the camera date from the year 1824; and in 1829 these two great
originators of sun-drawings entered into partnership for mutually
investigating this enchanting art. In 1827 Niepce had presented an
article to the Loyal Society of London on this subject; but as yet
Daguerre had not arrived at any successful results, nor had be
published any thing in reference to them. The process of Daguerre
aimed to perform the same operation by the same method, that is, by
light; the materials for the sensitive surface, for developing and
fixing alone, being different. Iii this process are found the use of
the camera, iodide of silver on a metal plate, mercury as a
developer, and hyposulphite of soda as a fixing agent; in that of
Niepce, bitumen on a metal plate, iodine as a developer, and oil of
lavender in place of the hyposulphite of soda. The use of the latter
substance was probably suggested to Daguerre by the publication of a
paper, by Sir John Herschel, on the solubility in this menstruum of
the insoluble salts of silver. The image formed on the iodized
surface was quite latent until brought out by the vapor of
mercury. It seems wonderful how Daguerre should hit upon the idea of
using this vapor, or that a latent image was on the surface. Knowing
the latter and the possibility of such a development, the chemist
has only to persevere in a systematic exploration among the infinite
number of chemical substances, in order finally to meet with
success; but Daguerre could not à priori be furnished
with such positive knowledge; hence our admiration at his success,
at the hardihood and perseverance of his character in search of this
success, can not be otherwise than boundless. Niepce, too, is
entitled to an equal share of honor; for without Niepce, in all
probability, sun-drawing would still be a latent property of nature;
as also, without Daguerre, the discoveries of Niepce would not stand
out in that bold relief in which they are now exhibited.
The plates which Daguerre used for the reception of the
heliographic image were of silver, or of copper plated with silver.
The silver surface, highly polished, was subjected to the vapor of
iodine in the dark-chamber; the iodide of silver thus formed being
very sensitive to the actinic influence, the plate was ready for the
reception of the latent image. This mode of sensitizing the surface
had reduced the time of exposure from hours to minutes; and an
increase of sensitiveness was attained at the suggestion of Fizeau,
who recommended the use of bromine-water; and about the same time
the chloride of iodine was recommended as an accelerator by Claudet;
and the bromide of iodine by Gaudin. By means of these accelerators
the time was again reduced from minutes to seconds. In this state of
perfection we will now leave the art of heliography, or of the
Daguerreotype as it is more frequently denominated, and observe
only, in conclusion, that this discovery of Daguerre was reported to
the world in January, 1839; but the process was not communicated
until after a bill had been passed by the French government, which
secured to Daguerre a pension of six thousand francs a year, and to
Isidore Niepce, the son of Daguerre's partner, an annual pension for
life of four thousand francs, one half of which was to revert to
their widows.
That Mr. Fox Talbot was acquainted with the experiments of Niepce
and Daguerre is very doubtful, because the result of these
experiments was kept secret until the pensions had been granted; but
Mr. Talbot states, in the communication which he made to the Royal
Society on the thirty-first of January, 1839, six months before the
publication of Daguerre's process, that he had been applying the
property of discoloration of the silver salts by light. to useful
purposes. This application consisted in preparing a sensitive paper
for the copying of drawings or paintings, by direct contact. The
paper was dipped, in the first place, in a solution of chloride of
sodium, and afterward in one of nitrate of silver, whereby a film of
chloride of silver was formed--a substance much more
sensitive to light than the nitrate of silver, which had heretofore
been employed for photographic purposes. The object to be copied,
which had to be transparent, or partly so, was applied in direct
contact with the sensitive paper, and exposed to the ray's of the
sun. By this means, a copy of the object was obtained, in which the
lights and shades were inverted. This was the negative,
which, when fixed, was superimposed on another piece of the
sensitive paper, and exposed in its turn to the rays of light,
whereby a positive print was obtained of the object, in which
the lights and shades were exhibited in their natural position.
The communication of Talbot is the first, which laid the
foundation of multiplying copies of a picture by the combined action
of light and chemical material; it gave the first idea of
photographic printing.
In the year 1841 another method was devised and patented, called
Talbotype or Calotype. The process consisted in
preparing paper with the iodide of silver, which, when
exposed to light, became the recipient of a latent image, which
afterward was made to appear by the application of a developer, and
was fixed with hyposulphite of soda. This method is the essential
point in the present collodion process; it is, in fact, the very
foundation of photography. Talbot, therefore, merits an equal
position in history with Niepce and Daguerre. These three-this much
to be honored trio-are the undisputed originators of that branch of
natural science which hereafter will occupy a prominent part of
human intelligence.
The paper, in the Calotype process, was immersed in a solution of
iodide of potassium, or floated on its surface; as soon as dry, it
was floated on a solution of nitrate of silver for a certain time.
By this operation, a film of iodide of silver was formed by the
double decomposition of the two salts in contact. The excess of
iodide of potassium, or of nitrate of silver and the nitrate of
potassa were afterward removed by washing in several waters. These
operations had to be performed in the dark chamber, by the aid of a
small candle or lamp. When the paper was required to be used, it was
brushed over with a solution of one part of nitrate of silver,
containing fifty grains to the ounce, two parts of glacial acetic
acid, and three of a saturated solution of gallic acid; or the paper
was floated on the surface of this gallo-nitrate of silver,
as it is called, for a few seconds, and the excess of fluid removed
by blotting-paper. By this mode of treatment, the paper was rendered
very sensitive, sufficiently so to receive an impression of a living
person, by means of the camera obscura. An exposure of one second,
or of a fraction of a second, was found effective in producing: an
impression on the Calotype paper. This impression might be totally
invisible, partly visible, or distinctly visible, according to the
circumstances of time, intensity of the light, and sensitiveness of
the prepared paper. The latent image, or partially visible image,
was then developed to any degree of depth of shades, by washing the
surface of the paper with one part of a solution of nitrate of
silver, of the same strength as before, and four parts of the
saturated solution of gallic acid. The image gradually becomes
developed by this treatment, and in a few minutes reaches its
maximum degree of intensity. The fixing solutions were bromide of
potassium and hyposulphite of soda. The first impression, thus
obtained, was in this process, as well as in that with chloride of
silver, a negative, which, by continuing the process and
using this negative as an original object, either in the camera or
by direct application, produced a positive, with the lights
and shades in their appropriate positions.
The difficulty in this process is the want of homogeneity, and of
a sufficient transparency, in the structure of paper. The want of
transparency probably was regarded the greatest drawback in the
production of negatives; whilst the irregularities in the fiber of
the paper could never yield a surface to compete with the brilliant
and even surface of a polished piece of silver for the reception of
positive pictures. To obviate these disadvantages, Sir John Herschel
proposed the use of glass plates, and was the first to employ
them.
In the year 1847 Niepce de St. Victor, the nephew of Daguerre's
partner, to whom we are indebted for many interesting publications
on the Chromotype, managed to fix a film of albumen on the glass
plates. This film is intimately mixed with the iodides or bromides,
and flowed upon the surface of the glass. Such albumen plates are
employed by many very distinguished artists at the present day, who
exhibit specimens of fine and sharp definition and softness of tone
in their stereographs, that have not been surpassed by any other
process; as, for instance, regard those beautiful productions of
Ferrier.
The next important improvement in photography was effected in
1851; it is the foundation-stone of a new era. Legray originally
suggested that collodion might be used as the receptacle of the
sensitive material, in place of albumen; but we are indebted to
Archer for the practical application of the solution of gun-cotton,
and of the mode of employment, pretty much as it now stands. Archer
substituted pyrogallic acid for the gallic acid that had been
previously used in the development of the latent image. Pyrogallic
acid, although still used as a developer, has been since pushed
aside, in a great measure, by another substitute, the sulphate of
the protoxide of iron, at the Suggestion of Talbot. It is now
limited principally to the operation of intensifying.
Collodion is a solution of a substance very much resembling
gun-cotton in ether and alcohol. A decided improvement, in many
respects, has been made in this solution, at the suggestion of
Sutton, the editor of the Photographic Notes, who recommends
an excess of alcohol. When this solution is poured upon a piece of
clean glass, it forms a very thin, even, and transparent film, which
quickly dries, and can scarcely be distinguished from the surface of
the glass beneath it. It contains the materials for sensitization.
The discovery and application of this substance have given rise to
what is denominated the collodion process. It is impossible
to calculate the impetus given to photography by this discovery, or
its value to society, in the promotion of comfort and happiness;
much less can an idea be conceived of the resources to which it may
give rise by its future developments.
In the year 1838 or 1839, Mr. Mungo Ponton pointed out a very
important discovery in reference to bichromate of potassa, when
acted upon by light, whereby this salt, the chromic acid, or (as Mr.
Talbot advances) the organic matter with which the salt is in
combination, becomes insoluble. The paper for experimenting on this
point is uniformly coated with a mixture of bichromate of potassa,
gelatine, and lampblack in cold distilled water, and allowed to dry
in the dark room. When dry, it is ready to be placed beneath a
negative. The time varies from four or five minutes to a quarter of
an hour or upward. The impression obtained in this way is quite
latent, and is made to appear by dissolving off, with hot water,
those parts that have been entirely or partially excluded from the
actinic influence of the light. The picture resulting from this
treatment is a positive print, in black and white, of which the
shades are produced by the carbon of the lampblack. This discovery
gave rise to carbon-printing.
In the year 1852 a patent was taken out in England by Talbot,
reserving to himself the sole use of bichromate of potassa and
gelatine in the production of photo-engravings on steel. Three years
after this date, that is, in 1855, Poitévin patented a
process for making carbon prints by means of the same materials
combined with coloring matter, as well as for obtaining a
photographic image on a lithographic stone, capable of being printed
from by the ordinary lithographic press. In Talbot's process the
steel plates were covered with a coating of bichromate of potash and
gelatine, the operation taking place in the dark chamber. A
transparent positive is then placed on its surface, and the plate is
then exposed to the light. The latent image is developed as before
alluded to. Afterward the edges of the plate are raised with wax, or
some resinous preparation, so as to form a sort of dish, into which
is poured the acid or etching-fluid, which etches away the parts
exposed by the removal of the soluble gelatine. The etching-fluid
used by Talbot was the bichloride of platinum. Poitévin's
process is in principle the same. The disadvantage in the latter
process arises from the want of durability in the image, which,
being formed out of organic matter lying, as it must do, between the
ink and the stone, is liable to be soon abraded after a few pictures
have been printed from it. These attempts have created a number of
improvements, by which matrixes can now be furnished, by the aid of
photography, for the engraver's press, the lithographic press, and
the typographic press.
Messrs. Cutting and Bradford took a patent out, in this country,
for a process in which the image is formed directly of greasy ink
used in lithography.
The next important step in photo-lithography is that in which the
picture is first formed by bichromate of potash and gelatine on
lithographic transfer-paper, that is, paper coated with a
layer of albumen. A negative is placed in direct contact with paper
so prepared, from which an image is obtained, that is, after certain
other operations, transferred directly, in lithographic ink, to the
stone. This process was patented in 1859, at Melbourne, in
Australia, by Mr. Osborne, for which he was awarded by the
government of the colony of Victoria the sum of one thousand pounds.
This process promises to be the basis of the most successful
operations in photo-lithography.
Asser, of Amsterdam, invented or used the transfer process at the
same time that Osborne was using it in Australia.
Colonel Sir Henry James makes use of zinc, upon which he
transfers the image formed in ink; the image having been produced on
engraver's tracing-paper by the means adopted by Talbot,
Poitévin, and Osborne.
In the year 1859 another process for photo-lithographic purposes
was patented in Vienna, in Austria, in which asphaltum is again
brought into the field. The developer is oil of turpentine and
water. The latent image is produced in a film consisting of a
solution of asphaltum in chloroform, by means of a collodion
negative exposed for a number of hours. As soon as the soluble
asphaltum has been removed, the remaining insoluble parts which form
the shades of the image are coated with a layer of ink by the
printer; the image is then gummed in, and slightly etched; after
which it is ready for the press.
Poitévin has just published a new method of direct
carbon-printing on paper. It depends upon the insolubility
communicated to certain organic matters, such as gum, albumen,
gelatine, etc., by the per-salts of iron, and on a new fact observed
by him, namely, that this matter, coagulated and rendered insoluble
in cold and even in hot water, becomes soluble under the influence
of light, and in contact with tartaric acid, which, by the reduction
of the iron salt, restores to the organic matter its natural
solubility. The paper for carbon-printing is floated in a bath of
gelatine dissolved in water and colored with a sufficient quantity
of lampblack, or other coloring matter, and maintained at a lukewarm
temperature. The paper becomes thus uniformly covered with the
colored gelatine.
The sensitizing part is performed in the dark room by plunging
each sheet into a solution of sesquichloride of iron and tartaric
acid in water. By this immersion the gelatine becomes quite
insoluble even in boiling water. The sheets are taken out and dried.
The prints are obtained by placing transparent positives in direct
contact with the paper in the printing-frame Two or three minutes'
exposure to the rays of the sun will be found sufficient to render
those parts through which the light has passed soluble in boiling
water, which is the developer and fixing agent at the same time. A
little acid water is used toward the end of the washing, in order to
remove all traces of the ferruginous compound.
Poitévin has other methods of producing direct
carbon-prints, which, together with this and others preceding, will
be fully discussed in their proper place.
Niepce de St. Victor has long been experimenting in his favorite
study of the chromotype. He has succeeded in producing photogenic
impressions endowed with certain colors of the original. Yellow is
found very difficult to transfer to the heliochromic plate at the
same time with other colors. Red, green, and blue, it appears, could
be formerly reproduced satisfactorily. In the fifth memoir of Niepce
on this subject, the author states that he can now reproduce yellow
along with other colors in a definite manner. The trouble with these
heliochromic specimens is still their want of permanence. At the
very most, the colors can not be preserved longer than two or three
days. The problem to be settled is the means and mode of
fixation.
Notes
1 Dolland, J., was born in
London, in the year 1706, and died in 1762.
2 Scheele, Charles William, was
born on the nineteenth of December, 1742, at Stralsund, Sweden. He
died on the twenty-first of May, 1786, at Koeping, on Lake
Moeler.
3 Bitter, John William, was born
at Samitz, in Silesia, in 1 776, and died in 1810.
4 Wollaston William Hyde M.D.,
was born on the sixth of August, 1766, at East-Dereham, and died
December twenty-second, 18´).8, in London.
5 Wedgwood, Josiah, was born at
Newcastle-under-Lyne, in 1730, and died in the year 1795.
6 Sir Humphry Davy was born at
Penzance, in 1778, and died at Geneva, in 1828.
7 Niepce,
Joseph-Nicéphore, was born at Chalon-sur-Saône, and
died in 1833.
8 Daguerre, L.J.M., was born at
Cormeilles, in 1787, and died in 1851.
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